ISO INTERNATIONAL STANDARD 19830 Firstedition 2015-11-15 Surface chemical analysis Electron spectroscopies - Minimum reporting requirements for peak fitting in X-ray photoelectron spectroscopy Analysechimiquedessurfaces-Spectroscopied'électrons- Exigencesminimalespourlerapportd'ajustementdepicen spectroscopiedephotoelectronsX Referencenumber ISO19830:2015(E) ISO Intermational Organization for Standardization @IS02015 JIANG INST OF STANDARDIZATION C15956617 d without license from IHS IS019830:2015(E) COPYRIGHTPROTECTEDDOCUMENT IS02015,PublishedinSwitzerland All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below or ISO's member body in the country of the requester. ISo copyright office Ch. de Blandonnet 8.CP 401 CH-1214 Vernier, Geneva, Switzerland Tel. +41 22 749 01 11 Fax +4122 749 09 47 [email protected] www.iso.org Uicensee-ZHEJIANG INST OF STANDARDIZAoISQ,5-All rights reserved etworking permitted without license from IHS Not for Resale, 2016/1/8 01:57:4 IS019830:2015(E) Contents Page Foreword ..V Introduction.. ..vi 1 Scope.. 2 Terms and definitions 3 Symbols and abbreviated terms 2 3.1 Abbreviated terms. 2 3.2 .2 Symbols..... 4 Reportingofrelevantdata acquisitionparameters. .3 4.1 General. .3 4.2 Spectrometer .3 4.3 Instrumentresolution .3 4.4 Detector. .3 4.5 X-ray source 4 4.6 Elementidentity .4 4.7 Energy range in the spectrum 4 4.8 Energy step size in spectrum. .4 4.9 Charge compensation. .4 5 Reporting of single-spectrumpeak-fittingparameters .5 5.1 General .5 5.2 Background range... .5 5.3 Background integration range .5 5.4 Background type. 5.5 Applicationofafittedbackground 5 5.6 Setting the peak parameters. .6 5.7 Peak area and peak height. 6 5.8 Peak area and peak height ratios .6 5.9 Full width at half maximum. 6 5.10 Peakshape 6 5.11 Peak asymmetry parameters. .7 5.12 The peak-fitting process > 5.13 Residual spectrum. 7 Multi-spectrum peak fitting .1 6 6.1 General 1 6.2 Peakfittingmethodsformulti-spectrumdata sets 6.3 Propagation of constraints .8 6.4 Background propagation. .8 7 Satellite subtraction ..9 8 Doublet subtraction 9 Spectrum deconvolution ..10 10 Fitqualityand uncertainties .10 10.1 General. .10 10.2 Fit quality.... ..10 10.3 Uncertainty in the reported binding energies ..10 10.4 Uncertainty in the peak areas ..10 AnnexA(informative)Exampleofreportingpeakfitting ..1 Annex B (informative) Reporting peak fitting for multi-level data sets ..14 Annex C (informative) Template for reporting peak fitting parameters ..17 AnnexD (informative)Statistical methods. ..19 iii Licensee=ZHEJIANG INST OF STANDARDIZATION C1 5956617 ithoutlicense from IHS